In this paper I undertake the structural analysis of exclamative clauses with wh-item ``que``. Wh-exclamatives are quite similar to wh-interrogatives. But interrogative clause and exclamative clause are different in clausal type and its function. So I propose that wh-phrases of interrogative clauses occupy the different position from that of exclamative clauses. Within the theoretical perspective of the fine structure proposed by Rizzi(1997), I focus on the relative order of wh-phrases of exclamative clauses and interrogative clauses in left peripheral structure. Based on the Spanish experimental evidences, I intend to verify the structural relation among topic elements, focus elements and wh-constituents of exclamative clauses and interrogative clauses. I will show the landing site that wh-phrases of exclamative sentences target with respect to word order variation. Furthermore, I will investigate the syntactic properties of complementizer ``que`` optionally derived in exclamative construction. I will identify the position of complementizer ``que`` in exclamative clauses as the element that maintains Spec-head configuration with wh-exclamative.