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> 한국공업화학회 > 응용화학 > 2권 1호

실로산 가교와 우레탄 가교 고체고분자 전해질의 열 및 전도특성

The thermal and conductive properties of the siloxane and urethane crosslinked solid polymer electrolytes

정태화 , 권종옥 , 노시태 ( Tae Hwa Jeong , Jung Ohk Kweon , Si Tae Noh )

- 발행기관 : 한국공업화학회

- 발행년도 : 1998

- 간행물 : 응용화학, 2권 1호

- 페이지 : pp.1-4 ( 총 4 페이지 )


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논문제목
초록(외국어)
Crosslink in solid polymer electrolytes(SPE) affect the improvement of mechenical properties, the destruction of crystallinity, and the elevation of conductivity. We investigated two types of SPE films which have different crosslinking structures. First, siloxane crosslinked SPE films prepared by sol-gel method have inorganic filler. Second, urethane crosslinked SPE films have the simple chemical crosslink. It has been known that inorganic-filled SPE films have excellent thermal, electrical stability and mechnical properties. In this study, we investigated the thermal and conductive properties of the SPE films having siloxane crosslink or urethane crosslink with the change of temperature and salt contents. We could prepare transparent and amorphous polymer electrolyte films. With the increase of salt content T_g increased. Comparing PEG600 to PEG1000, the T_g of PEG1000 was lower than that of PEG600. The T_g of urethane crosslink was lower than that of siloxane crosslink for PEG600. LiClO₄ was used as salt. In futher study, we will investigate the thermal and conductive properties with the inter-crosslink molecular weight of urethane crosslink.

논문정보
  • - 주제 : 공학분야 > 화학공학
  • - 발행기관 : 한국공업화학회
  • - 간행물 : 응용화학, 2권 1호
  • - 발행년도 : 1998
  • - 페이지 : pp.1-4 ( 총 4 페이지 )
  • - UCI(KEPA) : I410-ECN-0102-2009-570-007307225
저널정보
  • - 주제 : 공학분야 > 화학공학
  • - 성격 : 학술지
  • - 간기 : 반년간
  • - 국내 등재 : -
  • - 해외 등재 : -
  • - ISSN : 1226-8801
  • - 수록범위 : 1997–2013
  • - 수록 논문수 : 2399